Questions tagged [wavefunction]

A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state. DO NOT USE THIS TAG for classical waves.

The wavefunction is a complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state.

In the Schrödinger Wave formulation of Quantum Mechanics, the wavefunction can be determined by the , which, in its most general form, can be stated as:

$$\hat H|\Psi\rangle=i\hbar\frac{\mathrm d}{\mathrm d t}|\Psi\rangle$$

In the case of a "Euclidean Hamiltonian" given by the operator $\hat H=\dfrac{\hat P^2}{2m}+\hat U$, this becomes:

$$\left(\frac{\hat P^2}{2m}+\hat U\right) |\Psi\rangle=i\hbar\frac{\mathrm d}{\mathrm d t}|\Psi\rangle.$$

Since the momentum operator $\hat P$, in the position bases, is $-i\hbar\nabla$, the Schrödinger equation becomes $$\left(-\frac{\hbar^2}{2m}\nabla^2+U\right)\Psi= i\hbar\frac{\partial\Psi}{\partial t} $$ with $\Psi=\langle x|\Psi\rangle$.

This is known as the time-independent Schrödinger equation. Note that as the Hamiltonian used was Euclidean, this equation is, in fact, non-relativistic. The relativistic version of this equation in Relativistic Quantum Mechanics (and also in , but there it describes spin-1/2 fields) is the .

The wavefunction also appears in Feynman's formulation of Quantum Mechanics. In the Path Integral formulation, a functional, called the phase, is associated with each path:

$$\phi = A e^\frac{iS}{\hbar}.$$

The Kernel, or the Matrix Element, is the path integral of this phase.

$$K(x ) =\int\phi\mbox{ } \mathcal{D}x.$$

The wavefunction, finally, is given by:

$$\Psi(x)=\int_{-\infty}^\infty \left(K(x,x_0)\Psi(x_0) \right) \mbox{d} x_0.$$

It is often surprising to many that the absolute value of the phase squared, $|\phi|^2$, is constant for all paths at $A^2$. However, this actually makes sense, as the position of the particle is initially completely well-defined, so Heisenberg's Uncertainty Principle tells us that we would have no idea about the momentum and thus no idea about its future position. However, the next moment, you know absolutely nothing about its momentum, and so on. This process coarse-grains a particular path, the classical path, which means it is much more probable than the other paths.

The mathematical description of this can be obtained by standard procedures (c.f. Feynman, Hibbs, Styer "Quantum Mechanics and Path Integrals", pg 77 - 79), and the final result is the Schrödinger's Equation.

DO NOT USE THIS TAG for classical waves. Use the tag instead.

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About the complex nature of the wave function?

1. Why is the wave function complex? I've collected some layman explanations but they are incomplete and unsatisfactory. However in the book by Merzbacher in the initial few pages he provides an explanation that I need some help with: that the de…
yayu
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Why is it impossible to measure position and momentum at the same time with arbitrary precision?

I'm aware of the uncertainty principle that doesn't allow $\Delta x$ and $\Delta p$ to be both arbitrarily close to zero. I understand this by looking at the wave function and seeing that if one is sharply peeked its fourier transform will be…
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Does Heisenberg's uncertainty under time evolution always grow?

Recently there have been some interesting questions on standard QM and especially on uncertainty principle and I enjoyed reviewing these basic concepts. And I came to realize I have an interesting question of my own. I guess the answer should be…
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What exactly is a bound state and why does it have negative energy?

Could you give me an idea of what bound states mean and what is their importance in quantum-mechanics problems with a potential (e.g. a potential described by a delta function)? Why, when a stable bound state exists, the energies of the related…
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Hilbert space vs. Projective Hilbert space

Hilbert space and rays: In a very general sense, we say that quantum states of a quantum mechanical system correspond to rays in the Hilbert space $\mathcal{H}$, such that for any $c∈ℂ$ the state $\psi$ and $c\psi$ map to the same ray and hence are…
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Why isn't the universe full of electrons?

The probability of an electron found outside the atom is never zero. Consider building an electron detector, it must receive permanent signals from all electrons in the universe, as they can exist everywhere. Of course the probability decreases with…
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Normalizable wavefunction that does not vanish at infinity

I was recently reading Griffiths' Introduction to Quantum Mechanics, and I stuck upon a following sentence: but $\Psi$ must go to zero as $x$ goes to $\pm\infty$ - otherwise the wave function would not be normalizable. The author also added a…
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What's the point of Pauli's Exclusion Principle if time and space are continuous?

What does the Pauli Exclusion Principle mean if time and space are continuous? Assuming time and space are continuous, identical quantum states seem impossible even without the principle. I guess saying something like: the closer the states are the…
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The formal solution of the time-dependent Schrödinger equation

Consider the time-dependent Schrödinger equation (or some equation in Schrödinger form) written down as $$ \tag 1 i\hbar \partial_{t} \Psi ~=~ \hat{H} \Psi . $$ Usually, one likes to write that it has a formal solution of the form $$ \tag 2 \Psi (t)…
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Why doesn't the nucleus have "nucleus-probability cloud"?

While deriving the wave function why don't we take into the account of the probability density of the nucleus? My intuition says that the nucleus is also composed of subatomic particles so it will also have probability cloud like electrons have. Do…
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What is the probability for an electron of an atom on Earth to lie outside the galaxy?

In this youtube video it is claimed that electrons orbit their atom's nucleus not in well-known fixed orbits, but within "clouds of probability", i.e., spaces around the nucleus where they can lie with a probability of 95%, called "orbitals". It is…
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What is a wave function in simple language?

In my textbook it is given that 'The wave function describes the position and state of the electron and its square gives the probability density of electrons.' Can someone give me a very simple example of a wave function with explanation?…
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Half-integer eigenvalues of orbital angular momentum

Why do we exclude half-integer values of the orbital angular momentum? It's clear for me that an angular momentum operator can only have integer values or half-integer values. However, it's not clear why the orbital angular momentum only has integer…
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Can someone provide a physical -- not mathematical -- intuition for the phase in a quantum wavefunction?

I've read every thread on StackExchange (and Quora and reddit...) that I can find about a physical intuition for the phase in the quantum wave function, and I still Just. Don't. Get. It. (Yes, I've seen this thread--didn't help!) As a jumping off…
QuantumFumbler
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The importance of the phase in quantum mechanics

In introductory quantum mechanics I have always heard the mantra The phase of a wave function doesn't have physical meaning. So the states $| \psi \rangle$ and $\lambda|\psi \rangle$ with $|\lambda| = 1$ are physically equivalent and…
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