Questions tagged [schroedinger-equation]

Partial differential equation which describes the time evolution of the wavefunction of a quantum system. It is one of the first and most fundamental equations of quantum mechanics.

When to use this tag

Use the tag if you have a question specifically relating to the Schrödinger equation, such as its derivation or the particular form of the Schrödinger equation for a given problem. In general, you will also want to tag your question as .

Introduction

The general, time-dependent Schrödinger equation is

$$ i \hbar \frac{\partial}{\partial t} \Psi(x,t) = \hat H \Psi $$

with the Hamiltonian $\hat H$ and the wave function $\Psi(x,t)$. For a single, non-relativist particle, this is equal to

$$ i \hbar \frac{\partial}{\partial t} \Psi(x,t) = \left( \frac{-\hbar^2}{2m} \nabla^2 + V(x,t) \right) \Psi(x,t) \quad .$$

If the potential $V(x,t)$ is not time-dependent, this equation separates and gives the time-independent Schrödinger equation, which is just the eigenvalue equation for the Hamilton operator:

$$ \hat H \Psi(x,t) = E \Psi(x,t) $$

The Schrödinger equation describes the time evolution of states/wave functions in the Schrödinger picture. If one instead chooses to work in the Heisenberg picture, where states are time-independent and instead operators change in time, the governing equation is

$$ \frac{\mathrm{d}}{\mathrm{d}t} \hat A(t) = \frac{i}{\hbar} [ \hat H , \hat A(t) ] + \frac{\partial}{\partial t} A(t) \quad.$$

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Why can't the Schrödinger equation be derived?

Honestly, I don't get it. People say it's because it's a postulate. But, I mean, I see people deriving the Schrödinger equation with the help of the wave function, $T+U$ and partial differentials in three space coordinates and one time coordinate.…
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How is the Schroedinger equation a wave equation?

Wave equations take the form: $$\frac{ \partial^2 f} {\partial t^2} = c^2 \nabla ^2f$$ But the Schroedinger equation takes the form: $$i \hbar \frac{ \partial f} {\partial t} = - \frac{\hbar ^2}{2m}\nabla ^2f + U(x) f$$ The partials with respect…
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In quantum mechanics, given certain energy spectrum can one generate the corresponding potential?

A typical problem in quantum mechanics is to calculate the spectrum that corresponds to a given potential. Is there a one to one correspondence between the potential and its spectrum? If the answer to the previous question is yes, then given the…
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Why can we treat quantum scattering problems as time-independent?

From what I remember in my undergraduate quantum mechanics class, we treated scattering of non-relativistic particles from a static potential like this: Solve the time-independent Schrodinger equation to find the energy eigenstates. There will be…
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How can one derive Schrödinger equation?

The Schrödinger equation is the basis to understanding quantum mechanics, but how can one derive it? I asked my instructor but he told me that it came from the experience of Schrödinger and his experiments. My question is, can one derive the…
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Does quantum mechanics violate the equivalence principle?

I have a question about equivalence principle in quantum mechanics. Consider a Schroedinger equation under gravitional field $$\left[ - \frac{1}{2m_I} \nabla^2 + m_g \Phi_{\mathrm{grav}} \right]\psi = i \partial_t \psi \tag{1} $$ where $m_I$ and…
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Does Heisenberg's uncertainty under time evolution always grow?

Recently there have been some interesting questions on standard QM and especially on uncertainty principle and I enjoyed reviewing these basic concepts. And I came to realize I have an interesting question of my own. I guess the answer should be…
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What exactly is a bound state and why does it have negative energy?

Could you give me an idea of what bound states mean and what is their importance in quantum-mechanics problems with a potential (e.g. a potential described by a delta function)? Why, when a stable bound state exists, the energies of the related…
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State collapse in the Heisenberg picture

I've been studying quantum mechanics and quantum field theory for a few years now and one question continues to bother me. The Schrödinger picture allows for an evolving state, which evolves through a unitary, reversible evolution (Schrödinger’s…
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Why isn't the universe full of electrons?

The probability of an electron found outside the atom is never zero. Consider building an electron detector, it must receive permanent signals from all electrons in the universe, as they can exist everywhere. Of course the probability decreases with…
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The formal solution of the time-dependent Schrödinger equation

Consider the time-dependent Schrödinger equation (or some equation in Schrödinger form) written down as $$ \tag 1 i\hbar \partial_{t} \Psi ~=~ \hat{H} \Psi . $$ Usually, one likes to write that it has a formal solution of the form $$ \tag 2 \Psi (t)…
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Is the Schrödinger equation derived or postulated?

I'm an undergraduate mathematics student trying to understand some quantum mechanics, but I'm having a hard time understanding what is the status of the Schrödinger equation. In some places I've read that it's just a postulate. At least, that's how…
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Can the Schrodinger equation describe planetary motion?

I was asked on an exam whether the Schrodinger equation can be used to describe planetary motion and my answer was "No, because the solutions are wavefunctions which give probabilities but everything can be exactly measured for large objects." Then…
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Heisenberg Uncertainty Principle Applied to an infinite square well

I appreciate the statement of Heisenberg's Uncertainty Principle. However, I am a bit confused as to how exactly it applies to the quantum mechanical situation of an infinite square well. I understand how to apply Schrödinger's equation and…
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Why does the Schrödinger equation work so well for the hydrogen atom despite the relativistic boundary at the nucleus?

I have been taught that the boundary conditions are just as important as the differential equation itself when solving real, physical problems. When the Schrödinger equation is applied to the idealized hydrogen atom it is separable and boundary…
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