Questions tagged [ground-state]

The ground state of a quantum/classical mechanical system is its lowest-energy state; the energy of the ground state is known as the zero-point energy of the system. When a quantum system has infinite possible ground states, it is gapless with massless modes; if a quantum system has finite ground states, it is known as gapped and potentially topologically ordered. The ground state of a quantum field theory is usually called the vacuum state or the vacuum.

The ground state of a quantum/classical mechanical system is its lowest-energy state; the energy of the ground state is known as the zero-point energy of the system.

If more than one ground state exists, they are said to be degenerate. Many systems have degenerate ground states. Degeneracy occurs whenever there exists a unitary operator which acts non-trivially on a ground state and commutes with the Hamiltonian of the system.

When a quantum system has infinite possible ground states, it is gapless with massless modes; if a quantum system has finite ground states, it is known as gapped and potentially topologically ordered. The ground state of a quantum field theory is usually called the vacuum state or the vacuum.

An excited state is any state with energy greater than the ground state.

According to the third law of thermodynamics, a system at absolute zero temperature exists in its ground state; thus, its entropy is determined by the degeneracy of the ground state. Many systems, such as a perfect crystal lattice, have a unique ground state and therefore have zero entropy at absolute zero. (It is also possible for the highest excited state to have absolute zero temperature for systems that exhibit negative temperature.)

Read the source from the Wiki page.

277 questions
34
votes
3 answers

Is the Ground State in QM Always Unique? Why?

I've seen a few references that say that in quantum mechanics of finite degrees of freedom, there is always a unique (i.e. nondegenerate) ground state, or in other words, that there is only one state (up to phase) of the Hamiltonian with the minimum…
28
votes
5 answers

Why is the ground state important in condensed matter physics?

This might be a very trivial question, but in condensed matter or many body physics, often one is dealing with some Hamiltonian and main goal is to find, or describe the physics of, the ground state of this Hamiltonian. Why is everybody so…
23
votes
4 answers

Why is the temperature zero in the ground state?

Consider the following statement: If we know that the system is in the ground state, then the temperature is zero. How does this follow from the statistical definition of temperature?
yarnamc
  • 1,281
20
votes
4 answers

Is it possible to reconstruct the Hamiltonian from knowledge of its ground state wave function?

Is it possible to "construct" the Hamiltonian of a system if its ground state wave function (or functional) is known? I understand one should not expect this to be generically true since the Hamiltonian contains more information (the full spectrum)…
18
votes
2 answers

What's the lowest nuclear charge $Z < 1$ that will support a bound two-electron ion $(Z,2e^-)$?

In my programming project I calculate the minimal energy of an atom with 2 electrons in the $L=0, S=0$ state, using a Hylleraas wave function. The values I find for $Z=2$ (He) and $Z=1$ (H$^-$) are in good correspondence with what can be found in…
17
votes
5 answers

What does the absence of a ground state physically mean?

What does it physically mean, if a model in quantum mechanics or in quantum field theory has no ground state? So I am talking about a Hamiltonian $H$ such that $\sigma(H)$ is bounded from below. So what is the physical difference, if $H$ has an…
15
votes
3 answers

Is ground state and vacuum state the same thing?

Vacuum state is the lowest possible quantum energy state but isn't this also the definition of the ground state?
14
votes
1 answer

Explicit nontrivial examples in quantum mechanics: ground state degeneracy

Ground state degeneracy occurs whenever there exists a unitary operator which acts non-trivially on a ground state and commutes with the Hamiltonian of the system. I just want to find a potential $V(\mathbf{r})$, not necessary the central potential,…
12
votes
3 answers

What is meant by the "lowest energy state" of an atom?

What do people mean when they say that when an atom has a full outer shell, it is in its "lowest energy state" and that this is the most "stable" configuration (thus it is not likely to react with other atoms)? I am a GCSE student and when…
12
votes
3 answers

How does the interacting vacuum $|\Omega \rangle$ enter the theory?

To calculate scattering amplitudes, we consider $$ A(i\to f) = \langle{f | \hat S|i} \rangle = \langle{f |\mathrm{e}^{ -\frac{i}{\hbar} \int_{-\infty}^{\infty} dt' H_{\mathrm{i}}(t')} |i}\rangle$$ $$ \equiv \langle{f(\infty) |\mathrm{e}^{…
11
votes
1 answer

Parent hamiltonian of AKLT state

Given a translationally invariant Matrix Product State (assuming periodic boundary condition) on $N$ sites of dimension $d$ each, which takes the form $\sum_{i_1,i_2\ldots i_N=1}^dTr(A_{i_1}A_{i_2}\ldots A_{i_N})|i_1,i_2\ldots i_N\rangle$, with…
11
votes
3 answers

Why do electrons in an atom 'fall' back to the ground state?

Why, after absorbing a photon does an atom's electron 'fall' back to its ground state (what causes it to immediately lose its absorbed energy)?
10
votes
2 answers

Topological ground state degeneracy of SU(N), SO(N), Sp(N) Chern-Simons theory

We know that level-k Abelian 2+1D Chern-Simons theory on the $T^2$ spatial torus gives ground state degeneracy($GSD$): $$GSD=k$$ How about $GSD$ on $T^2$ spatial torus of: SU(N)$_k$ level-k Chern-Simons theory? SO(N)$_k$ level-k Chern-Simons…
10
votes
1 answer

Polarisability of the hydrogen atom from second-order Rayleigh-Schrodinger perturbation theory

I am trying to work out the polarisability of the ground state hydrogen atom using second-order Rayleigh-Schrodinger perturbation theory, including the unbound states. I know the angular part can be evaluated easily and that only the $Y_{10}$ states…
10
votes
3 answers

Why is the ground state energy of particle in a box not zero?

I understand that we want to solve for non-zero values of wave function. I always thought that is to avoid the obvious answer to Schrodinger equation. But from physical standpoint, if we have a particle of mass $m$, is it really impossible for it to…
1
2 3
18 19