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I found this formula for a polytropic process, defined by $PV^n = {\rm constant}$, in a book:

$$C = \frac R{\gamma-1} + \frac R{1-n} $$ where $C$ is molar specific heat and $\gamma$ is adiabatic exponent. I do not know how it was derived, can someone guide me?

Urb
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user34304
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3 Answers3

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That $C$ is the specific heat for the given cycle, i.e. $$dQ=nCdT$$ This is for $n$ moles of gas.(not the $n$ you stated in question)

I will assume $$PV^z=\text{constant}$$

$$nCdT=dU+PdV$$ $$\int nCdT=\int nC_vdT+\int PdV$$

$$nC\Delta T=nC_v \Delta T+\int \frac{PV^z}{V^z}dV$$

As numerator is a constant, take it out!

Also note that $$P_iV_i^z=P_fV_f^z$$

$i = \text{initial}$

$f=\text{final}$

Focusing on integral only,

$$PV^z\int V^{-z}dV$$

$$PV^z\left[\frac{V^{-z+1}}{-z+1}\right]^{V_f}_{V_i}$$

Note that the $PV^z$ is same for initial and final step. So, we multiply it inside and do this ingenious work:

$$-\frac{P_iV_i^zV_i^{-z+1}}{-z+1}+\frac{P_fV_f^zV_f^{-z+1}}{-z+1}$$

$$-\frac{P_iV_i}{-z+1}+\frac{P_fV_f}{-z+1}$$

Note that $PV=nRT$

$$\frac{nR\Delta T}{-z+1}$$

where $\Delta T=T_f-T_i$

Final equation :

$$nC\Delta T=nC_v \Delta T+\frac{nR\Delta T}{-z+1}$$

$$C=C_v+\frac{R}{1-z}$$

This will bring you the original equation, you can find $C_v$ by

$$C_p/C_v=\gamma$$

$$C_p-C_v=R$$

Using $C_p=\gamma C_v$,

$$C_v\left(\gamma-1\right)=R$$

$$C_v=\frac{R}{\gamma-1}$$

Substituting in original equation,

$$C=\frac{R}{\gamma-1}+\frac{R}{1-z}$$

evil999man
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We can also derive the result without integration:

$ PV^n= \text{constant}$ can be written as $ TV^{n-1}=\text{constant} $ $$ nCdT=dU+PdV $$ Dividing this equation throughout by $ dT $, differentiating $ TV^{n-1} = \text{constant} $ with respect to temperature, and plugging $ \frac{dV}{dT} $ into the equation will give the desired result.

$$ nCdT=dU+PdV $$ $$ nC = \frac{dU}{dT}+ P\frac{dV}{dT} $$ $$ TV^{n-1} = \text{constant} $$ $$ V^{n-1} + (n-1)TV^{n-2} \frac{dV}{dT} = 0$$ $$\frac{dV}{dT} = -\frac{V^{n-1}}{(n-1)TV^{n-2}} = \frac{V}{T(1-n)}$$ $$ nC = \frac{dU}{dT}+ P\left(\frac{V}{T(n-1)}\right) $$

Using $PV = nRT$ and $dU = nC_VdT$, $$ nC = \frac{dU}{dT}+ \frac{PV}{T(n-1)}=nC_V + \frac{nR}{1-n}$$

Now $C_V = \frac{R}{\gamma - 1}$ $$ nC =n\frac{R}{\gamma - 1} + \frac{nR}{1-n}$$ $$ C =\frac{R}{\gamma - 1} + \frac{R}{1-n}$$

Harsh
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Though there are already answers, this was the high school way I was taught:
$$\Delta U=q+w \\ NC_v \Delta T=NC_m \Delta T + \frac{NR\Delta T }{n-1} \\ NC_v \Delta T + \frac{NR\Delta T }{1-n}=NC_m \Delta T \\ C_v + \frac{R }{1-n}=C_m.$$ Note that $N$ is the number of moles while $n$ is the $n$ in $pv^n=\text{constant}$.

redoc
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