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I have a spatial wave function here $$\psi(x)=\frac{1}{\sqrt{a\sqrt{\pi}}}e^{-(x^2/2 a^2)+ikx} \quad .$$

I calculated its position expectation value, and it's zero, as expected since it's a stationary state as $|\psi|^2$ depends only on $x$.

Why is the Ehrenfest theorem not applicable here? That is, why $\langle p\rangle$ is non-zero if $\langle x\rangle$ is constant?

DanielC
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1 Answers1

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Your wave function $$\psi(x)=\frac{1}{\sqrt{a\sqrt{\pi}}}e^{-(x^2/2 a^2)+ikx}$$ does not depend on time $t$ and as such is not a solution of the time-dependent Schrödinger equation $$i\hbar \frac{\partial\psi(x,t)}{\partial t}=H\psi(x,t).$$

But Schödinger's equation is a requirement of Ehrenfest's theorem. Therefore you cannot apply Ehrenfest's theorem with your time-independent wave function.