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The time evolution of any wave function is deterministically specified by the Schrödinger equation (unless measured).

However, particle creation is not allowed in quantum mechanics.

As I am unfamiliar with quantum field theory, what would be a brief outline of how QFT extends QM to allow for particle creation?

James
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In what ways QFT generalizes QM
The answer depends on what is understood by Schrödinger equation: if it is $$i\partial_t|\psi\rangle = H|\psi\rangle,$$ where $H$ could be any Hamiltonian operator, then this is also true in quantum field theory (QFT). However, in quantum mechanics (QM) the Hamiltonian $H$ is usually understood as non-relativistic, corresponding to what is classically particles (mostly electrons and protons), often one-particle or with interactions limited to electromagnetic ones. Thus, QFT extends QM in the following ways (the list is by no means comprehensive):

  • relativistic quantum theory
  • treating fermions and bosons on equal footing, as fields (in this sense QFT is also an extension of the classical field theory - aka electromagnetism)
  • providing coherent treatment of interactions for arbitrary number of particles and for electromagnetic, strong and weak interactions (I am not sure about the current status of the gravity)

Importantly, QFT is a quantum theory built from fundamental principles - like the universal symmetries - from which one naturally obtains many things that in QM had to be introduced ad-hoc - e.g., electron spin or various new particles.

Last but not least, QFT has introduced many new methods (diagrammatic expansions, path integrals, renormalization group) which turned out to be extremely useful for dealing with what is essentially "quantum-mechanical" problems - like those in solid state physics.

In what ways QFT does not generalize QM
What QFT doesn't do, is it doesn't question the postulates of quantum theory, which are routinely referred to as postulates of quantum mechanics - this is an example of equivocation, i.e., the use of term quantum mechanics to mean both non-relativistic quantum theory and quantum theory in general. In other words, it would be correct to say that QM is a non-relativistic limit of QFT, which itself is a sub-domain (or application) of general quantum theory.

J.G.
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Roger V.
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There have historically been a couple of ways to motivate QFT from QM, but one useful framework is that of first vs. second quantization.

First quantization

This is standard quantum mechanics. If we wish to analyze a physical system, we write down its Hamiltonian and then apply the various quantization substitutions. So we have the usual steps of, e.g., $p_x \to -i \hbar \frac{d}{dx}$. Then we use this quantized Hamiltonian in the Schrödinger equation and solve for the time evolution of the wavefunction

Conceptually, in first quantization, we have taken the idea of a particle in classical mechanics and substituted it for the idea of a wavefunction. In classical mechanics, a particle can take on any possible state in phase space. But in quantum mechanics, if the eigenbasis of the wavefunction is discrete, then the wavefunction will collapse into one of a set of quantum states when it is observed --- a particle cannot be found just anywhere in phase space. So the particle has become quantized.

However, crucially, in first quantization, we still treat the fields that the particle interacts with the same way we did classically. If the particle is in a quadratic potential, for example, the potential is treated as continuous.

Second quantization

The step that quantum field theory takes is that now the fields that a particle interacts with are quantized as well. As an example, let's consider the electron in a hydrogen atom. In standard QM we were content to just write down the classical Hamiltonian as:

$$ H = \frac{\textbf{p}^2}{2m} - \frac{e^2}{r} $$

and then just make the substitution of $\textbf{p} \to -i \hbar \nabla$

But in QFT, we now need to consider how the electron actually interacts with the electromagnetic field. In standard QM, the electron is just interacting with a continuous electromagnetic field. But in QFT, the electron can only interact with the field in discrete interactions. This is because the field is no longer continuous, but, just like the electron itself, can only exist in discrete states (what we call photons). The quantization of the electromagnetic field produces a new effect, the Lamb shift.

So QFT is a more principled kind of theory than standard QM. In standard QM, we have two kinds of things: wavefunctions and potentials. But in QFT, all you have is fields. These fields can only occupy quantized states, and we call a quantized state of a field a "particle." There are four special fields which will interact with other fields, and we call those special fields "forces." So conceptually, it's actually quite simple. The mathematical details, of course, are a different story....

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Unfortunately the idea of particle creation is really just a terribly confusing way to describe quantum field theory. Quantum Field theory doesn’t have particles. It has (guess it…) fields. The amplitudes of those fields are quantized, and, for historical reasons people have chosen to call (often delocalized, basis-dependent, and non-conserved) excitations in those fields as “particles”. This has led to tons of confusion and misconceptions.

So quantum field theory extends standard quantum mechanics in the same way classical field theory (electromagnetism, fluid dynamics) extends classical particle dynamics (billiards balls, point charges).

Particle theories are theories that predict the space time trajectories of localized (often infinitesimal in the model) particles. Field theories are theories that predict the amplitudes in space time of delocalized (often infinite in spatial extent) fields.

What is often call “particle creation and annihilation” in qft is better thought of as “the amplitude of a field changing”. In qft field amplitudes change due to interactions between different fields eg the electron and photon fields in quantum electrodynamics (qed).

For more on this viewpoint see https://arxiv.org/abs/1204.4616 "There are no particles, there are only fields" by Art Hobson

Jagerber48
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There are two things people can mean by "Quantum Field Theory".

One is that it's the theory of quantum physics of fields. The second is that Quantum Field Theory (often capitalised) = particle physics (where relativity also becomes important). The latter is an ancient notion that was a result of generations of physicists being raised on outdated texts like Peskin and Schroeder. Unfortunately, this view is still quite common, especially among high-energy physicists.

Being "Relativistic" is just saying the theory's symmetry group contain the Lorentz Group. Of course, there are quantum field theories that are non-relativistic, as one encounters all the time in condensed matter physics. Moreover, the question of "particles" vs "fields" is often really just a question of ontology that is often given to theories posthoc (ironically, by positivists). What is referred to as "Quantum Mechanics" can be viewed as a 1-dimensional quantum field theory (for a field $x(t)$ where you interpret the dimension as "time" and the value of the field as the "position".). Nothing stops you from giving it also a perturbative treatment and drawing Feynman diagrams. In this sense, quantum field theory generalises quantum mechanics.

Neither is renormalisation anything unique to "Quantum Field Theory". The often-told story of Renormalisation being about "infinities of Quantum Field Theory" is also terribly outdated. It is now much better understood to occur due to a historical premature assumption taken at the time that the QFTs that appeared in particle physics are well-defined at all energy scales. To see how it can also occur in Quantum Mechanics, see section 4.5 of David Tong's lecture notes 1. The modern understanding of these issues is in terms of the Renormalisation Group and effective field theories.

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However, particle creation is not allowed in quantum mechanics.

what would be a brief outline of how QFT extends QM to allow for particle creation?

There is nothing inherent about QFT that allows for particle creation: instead the important point is that when QFT is mentioned, people are often implicitly referring to relatvistic QFT and it's the introduction of relativity that allows for particle creation.

In textbook applications, QM enjoys Galilean symmetries which imply that mass is a conserved quantity and this fact forbids particle creation. In textbook applications, QFT instead enjoys the symmetries of special relativity, in which mass is no longer conserved and particle creation is kinematically possible.

This is not a general property of QFTs, though. There are many examples of non-relativistic QFTs which again forbid particle creation due to the same symmetry constraints which forbid it in QM.

The above is my answer to your direct question. I can't help but also write about how QFT extends QM in general, below.

General Relationship Between QFT and QM

QFT is a pretty straightforward generalization/extension of QM, despite the fact that it is not often presented this way in textbooks.

In QM, we are tracking degrees of freedom which depend on a single variable: time. For instance, point particles can be described by their positions $\vec{q}(t)$, from which we can form Hamiltonians $H(\vec{q}, \vec{p})$ and create states $|\Psi\rangle$ which evolve under $H(\vec{q}, \vec{p})$ according to Schrodinger's equation. $|\Psi\rangle$ predicts the probability of finding the system with any particular value of $q$.

In QFT, things are nearly the same. The only difference is that we are now tracking fields, $\phi(t, x)$ which are functions of both time and space. The rest proceeds as before: from $\phi(t,x)$ we can form Hamiltonians $H(\phi, \pi_\phi)$ and create states $|\Psi\rangle$ which evolve under $H(\phi, \pi_\phi)$ according to Schrodinger's equation. $|\Psi\rangle$ predicts the probability of finding the system with any particular value of $\phi$ for every point in space.

The main reason that QFT is not typically taught this way in textbooks is that the answers to questions of interest in QFT are usually more efficiently computed by other means, i.e. you don't need all the scaffolding of wavefunctions and Schrodinger's equation. Action- and path-integral-based methods are typically more convenient. For instance, using the wavefunction is a terrible way to compute the $S$-matrix which describes scattering events.

The one area I know of where so-called "Schrodinger-picture field theory" is used and the computation look roughly like their QM counterparts is cosmology where it falls under the (awesomely) named "wavefunction of the universe" method; see the Hartle-Hawking paper of the same name.

I think this viewpoint is briefly mentioned in Weinberg somewhere (as is almost all of QFT), but I couldn't find the section at the moment. I know it is discussed fairly extensively in this book by Hatfield.

user26866
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Quantum field theory explains why the particles of quantum mechanics behave as they do .For example it details why electric charges attract or repel each other .