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When we examine the monochromatic solution of the free Schroedinger equation:

$$\psi(t,\mathbf r) = e^{-i\left(\frac{ħk^2}{2m}\right)t}\left(Ae^{i\mathbf{k\cdot r}} + Be^{-i\mathbf{k\cdot r}}\right).$$

It is said that it is a linear combination of a left and a right moving wave.

But looking at the part independent of time, all we can see is a static pattern, where each point of space is associated to a complex number.

And the effect of the time dependent part is not more than making each point oscillates at a given frequency.

It becomes more clear changing the constants A and B:

$$A = \frac{C + D}{2}\; \text{and} \;B = \frac{C - D}{2}.$$

The solution turns to:

$$\psi(t,\mathbf r) = e^{-i\left(\frac{ħk^2}{2m}\right)t}\left(\frac{C}{2}(e^{i\mathbf{k\cdot r}} + e^{-i\mathbf{k\cdot r}}) + \frac{D}{2}(e^{i\mathbf{k\cdot r}} - e^{-i\mathbf{k\cdot r}})\right).$$

If we define:

$$X = \frac{C}{2}(e^{i\mathbf{k\cdot r}} + e^{-i\mathbf{k\cdot r}}),$$ $$Y = -i\frac{D}{2}(e^{i\mathbf{k\cdot r}} - e^{-i\mathbf{k\cdot r}}).$$

The spatial part can be translated to:

$$\psi(0,\mathbf r) = X + iY,$$

where:

$$X = C\cos(\mathbf{k\cdot r}),$$ $$Y = D\sin(\mathbf{k\cdot r}).$$

That is a parametric equation of an ellipse:

$$\frac{X^2}{C^2} + \frac{Y^2}{D^2} = 1.$$

So, the spacial part of the equation is a kind of mapping of each point of space over an ellipse.

If C = D the ellipse becomes a circle. In this case, we have $B = 0$, and the solution becomes:

$$\psi(t,\mathbf r) = e^{-i\left(\frac{ħk^2}{2m}\right)t}Ae^{i\mathbf{k\cdot r}}.$$

My question is: can such a function be called a travelling wave? Or a travelling wave can only be described using Fourier analysis?

I believe that it must have a starting and a final point in the space. And that points move along the time, defining what can be called the wave velocity. In this case it is necessary Fourier analysis to get zero behind and in front of the wave range.

Qmechanic
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2 Answers2

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Any superposition/linear combination of monochromatic left- and right-moving exponential waves is of course equivalent to a superposition/linear combination of sine and cosine waves, as OP demonstrated above.

However from the point of view of a 1D scattering experiment where wavepackets enter from (and leave to) spatial infinity, the travelling exponential form is closer related to a physical particle interpretation.

One may object that the probability density of an exponential monochromatic wave is constant in space & time, so how can we say it is travelling? Well, it can understood as an appropriate limit of travelling wave packets, as explained in this related Phys.SE post.

Qmechanic
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If the spatial part were to be multiplied by (for example) $\cos \left( \dfrac{\hbar k^2}{2m}t \right)$ this would be true. In this case you get a standing wave. But multiplying by $e^{-i\frac{\hbar k^2}{2m}t}$ yields a travelling wave.

Milan
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