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I have a problem understanding the solution provided for the problem here:

the problem and the solution

It's from the book "Quantum Mechanics - Concepts and Applications", 2nd ed., by N. Zettili (Wiley, 2009).

My issue is that I don't understand the second equality of eq. (6.223). Why do these two integrals cancel each other out?

Qmechanic
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user159729
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1 Answers1

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Hints to show second equality of eq. (6.223):

  1. Integrate by parts twice as suggested by Count Iblis in a comment.

  2. Argue that boundary terms at $r=\infty$ in eq. (6.223) are zero.

  3. Argue that $$U_{n\ell}(r) ~=~ O(r)\quad \text{for}\quad r\to 0.\tag{*}$$ Eq. (*) is more tricky, and shown in e.g. this, this & this Phys.SE posts.

  4. Use eq. (*) to argue that boundary terms at $r=0$ in eq. (6.223) are zero.

Qmechanic
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