The Wigner–Eckart theorem relates matrix elements of spherical tensor operators in the basis of angular momentum eigenstates to Clebsch–Gordan coefficients. Within a given subspace, a component of such operators behaves proportionally to the same component of the angular momentum operator itself. Do not use for plain Clebsch–Gordan decompositions.
The Wigner–Eckart theorem relates matrix elements of spherical tensor operators in the basis of angular momentum eigenstates to Clebsch–Gordan coefficients. Operating with a spherical tensor operator on an angular momentum eigenstate is then like adding a state with angular momentum to the state: Within a given subspace, a component of this operator behaves proportionally to the same component of the angular momentum operator itself.