If the ball rolls without slipping while slowing down, there must be:
- a net torque acting to reduce its rotation rate ($\tau = I \frac{d \omega}{d t}$) and
- a net force acting to reduce its velocity ($F = m \frac{d v}{d t} = mr \frac{d \omega}{d t}$).
Here torque is $\tau$, moment of inertia is $I$, angular speed is $\omega$, mass is $m$, and speed is $v$. The contact forces (friction and normal force) produce the net torque about the centre of mass of the ball. Thus their sum cannot act through that centre of mass.
It would be possible for a perfectly rigid ball to slow down via rolling friction, even though the normal force acts through the centre of mass, if slipping were allowed. However, the case in the illustration you provide relies on the deformation of the ball. Therefore the normal to the point of contact does not pass through the centre of mass and a net torque results.