I believe the intended meaning is: It's not the energy of the sunlight that's particularly useful—it's its low entropy.
First, some preliminaries: We always wish to have a system that can do useful work, e.g., run a water wheel, raise a weight, or generate electricity.
The catches are that energy is conserved (which you probably knew about) and also that entropy is "paraconserved" (which you might not have known about). Specifically, entropy can't be destroyed, but it is transferred when one object heats another (and it's also created whenever any process occurs, anywhere).
The problem with producing work arises because work doesn't transfer entropy, but heat transfer does (while also creating some entropy). Therefore, we can't simply turn thermal energy—such as the energy the Sun provides—into work; we must dump the accompanying entropy somewhere as well. This is why every heat engine requires not just a source of thermal energy (the so-called hot reservoir) but also a sink for entropy (the so-called cold reservoir).
In the idealized process, when we pull energy $E$ from a hot reservoir at temperature $T_\mathrm{hot}$, the corresponding entropy transfer is $$S=\frac{E}{T_\mathrm{hot}}.$$
Now we extract some useful work $W$ (by boiling water and running a steam turbine, for example), and we dump all that entropy into the low-temperature reservoir at temperature $T_\mathrm{cold}$ (using a nearby cool river to condense the steam, for example): $$S=\frac{E-W}{T_\mathrm{cold}} .$$
The energy balance works out: $$E-W=(E-W).$$ The entropy balance works out: $$\frac{E}{T_\mathrm{hot}}=\frac{E-W}{T_\mathrm{cold}}.$$ The efficiency is $$\frac{W}{E}=1-\frac{T_\mathrm{cold}}{T_\mathrm{hot}}.$$ And the higher the temperature of the hot reservoir, the more work $W$ we can pull out while satisfying the two conversation laws.
Now to the point: The Sun sends a lot of energy our way: around 1000 W/m² at the earth's surface.
But is this in fact all that much energy?
The heat capacity of water is about 4000 J/kg-°C, so if we simply extracted 1°C worth from 250 g of water per second, we'd match the Sun in energy. Well, per square meter of sun exposure, at least, but there's a lot of water available on the planet, and its absolute temperature is pretty high (283 above absolute zero, more or less, in divisions of °C).
Even better, water is self-circulating, so in this scenario, we could cool seawater and let it recirculate.
As Gerd Ceder memorably put it, we could operate a party boat: pull out thermal energy from water to make ice for our cocktails, and use the extracted energy to cruise around all day.
Unfortunately, the restrictions described above tell us that we can't perform this extraction: there's no lower-temperature reservoir to send the entropy to (here, I'm assuming that most of the earth and atmosphere available to us is at around 10°C). In contrast, the Sun's temperature is enormous—around 5500°C, which makes the denominator of the effective entropy term $S=E/T$ quite small. Thus, it's not the energy of the sunlight that's particularly useful—it's its low entropy.