I have a problem with the transition from quantum relativistic wave equations (specifically Klein-Gordon equation) to QFT, since a lot of assumptions seem implicit. For example I have a problem with the time evolution operator, which is crucial on deriving the perturbative expansion $-$ the main tool in QFT I believe. c So here's what I have a problem with: when we make the leap from Schrödinger equation to a Klein-Gordon equation, we get a second order time derivative, and hence loose the simple concepts from nonrelativistic QM like: the Hamiltonian, time evolution operator etc.
But for a scalar quantum field we can make a Lagrangian density:
$$ \mathcal{L}(x) = \hbar^2 c^2 g^{\mu \nu} \partial_\mu \phi \partial_\nu \phi^* - m^2c^4 \phi \phi^* $$
and perform the "second quantization", from which we get a Hamiltonian, canonical commutation relations and the ability to use pictures (Schrödinger's, Heisenberg's...).
So how does this work? Before there was no Hamiltonian in principle, and now there is. Is this the Hamiltonian we pluck into the perturbative expansions' formulas? What changed, when compared to the single solution wave equation in the beginning?