I have some applications (for example LibreOffice) which looks really weird, design like from 90's.
How can I fix it, please?
You need to change your theme.
Either via gtk https://elementaryos.stackexchange.com/questions/1103/how-can-i-make-libreoffice-look-better
Or you install a theme directly http://www.debugpoint.com/2016/08/quick-tip-change-the-default-libreoffice-look-and-feel/
Most application use the general theme you set. You can change the theme in the kde settings.