In the quantum process formalism, we assume that we begin with a product state $$\rho \otimes |e_0\rangle \langle e_0|$$ where $\rho$ is a mixed state in a system of interest and where $|e_0\rangle$ is a pure state of the environment. This seems like a generous assumption however since the system could be entangled with the environment.
Nielsen and Chuang mention in section 8.2.2 that the quantum process formalism works even in the case where system and environment are entangled, but I haven't been able to find a good justification for this.
Why is it safe to make this assumption?
Here's my best guess:
Suppose we have a state $\sigma_{s, env}$ where the system $s$ is entangled with the environment $env$. A quantum channel over $\rho:=\mathrm{Tr}_{env}(\sigma_{s, env})$ can be understood as a unitary evolution of $\sigma_{s, env}$:
$$U \sigma_{s, env} U^\dagger$$
I think (but I don't know) we can always cook up a unitary $V$ such that
$$V\sigma_{s,env}V^\dagger = \rho\otimes|e_0\rangle\langle e_0|$$
Where $|e_0\rangle$ is a pure state of the environment. If this is the case, we then have:
$$ UV \Big(\rho \otimes|e_0\rangle\langle e_0| \Big)V^\dagger U^\dagger$$
Which suggests to me that we can always "move" any initial entanglement out into the unitary transformation and call it a job done.
Is this basically correct or is there more to it?