The following seems to work: consider in $\mathbb{C}^3\otimes\mathbb{C}^3$ the operator:
$$W \equiv \frac{I - 2\mathbb{P}(|\Psi^-\rangle)}{2}
= \begin{pmatrix}
1 & 0 & 0 & 0 & 0 & 0 & 0 & 0 & 0 \\
0 & 0 & 0 & 1 & 0 & 0 & 0 & 0 & 0 \\
0 & 0 & 1 & 0 & 0 & 0 & 0 & 0 & 0 \\
0 & 1 & 0 & 0 & 0 & 0 & 0 & 0 & 0 \\
0 & 0 & 0 & 0 & 1 & 0 & 0 & 0 & 0 \\
0 & 0 & 0 & 0 & 0 & 1 & 0 & 0 & 0 \\
0 & 0 & 0 & 0 & 0 & 0 & 1 & 0 & 0 \\
0 & 0 & 0 & 0 & 0 & 0 & 0 & 1 & 0 \\
0 & 0 & 0 & 0 & 0 & 0 & 0 & 0 & 1 \\
\end{pmatrix},$$
where $\{|0\rangle,|1\rangle,|2\rangle\}$ span each of the two qutrit spaces. This $W$ is a witness because it has the form $W=\alpha I-\mathbb{P}(|\Psi^-\rangle)$ with $\mathbb{P}(|\Psi^-\rangle)$ projection onto $|\Psi^-\rangle\equiv\frac{|01\rangle-|10\rangle}{\sqrt2}$, and $\alpha=\frac12$ the largest (squared) Schmidt coefficient of $|\Psi^-\rangle$.
Its action is trivial on all computational basis states except for
$$W|01\rangle=|10\rangle, \qquad W|10\rangle=|01\rangle.$$
It's also (at least) weakly optimal because $\langle \mathbb{P}_{01},W\rangle=\langle \mathbb{P}_{10},W\rangle=0$, and it's a proper witness because it detects $|\Psi^-\rangle$ as entangled.
However, it's not optimal, because denoting with $P_W$ the set of product states $|e,f\rangle$ such that $\langle \mathbb{P}_e\otimes\mathbb{P}_f,W\rangle=0$, as per the results mentioned here, one can observe that $|2,2\rangle$ isn't in the span of $P_W$. That's because for $|2,2\rangle$ to be spanned by vectors in $P_W$ one would need vectors in there of the form $|e\rangle\otimes|f\rangle$ where both $|e\rangle$ and $|f\rangle$ have nonzero overlap with $|2\rangle$. But then, expanding the expectation value, that would produce terms of the form $|\langle 2,f\rangle\langle 2,e\rangle|^2$, which can't be zero. Thus $|2,2\rangle$ is not spanned by $P_W$.
The projection $P\equiv \mathbb{P}_{2,2}\equiv \mathbb{P}_2\otimes\mathbb{P}_2$ is then a positive semidefinite nonzero operator such that
$$W-P = \begin{pmatrix}
1 & 0 & 0 & 0 & 0 & 0 & 0 & 0 & 0 \\
0 & 0 & 0 & 1 & 0 & 0 & 0 & 0 & 0 \\
0 & 0 & 1 & 0 & 0 & 0 & 0 & 0 & 0 \\
0 & 1 & 0 & 0 & 0 & 0 & 0 & 0 & 0 \\
0 & 0 & 0 & 0 & 1 & 0 & 0 & 0 & 0 \\
0 & 0 & 0 & 0 & 0 & 1 & 0 & 0 & 0 \\
0 & 0 & 0 & 0 & 0 & 0 & 1 & 0 & 0 \\
0 & 0 & 0 & 0 & 0 & 0 & 0 & 1 & 0 \\
0 & 0 & 0 & 0 & 0 & 0 & 0 & 0 & 0 \\
\end{pmatrix}$$
is still a witness. Hence $W$ isn't optimal.