They are not just related, they are identical, joined at the hip. I'll illustrate by the original legendary 2-flavor chiral model, with the chiral group $\text{SU}(2)_L \times \text{SU}(2)_R$. This group is spontaneously broken down to $\text{SU}(2)_V$, by the QCD vacuum: it is realized ''nonlinearly'', in the Nambu–Goldstone mode, i.e., the $Q_V$ annihilate the vacuum, but the $Q_A$ do not! This is visualized nicely through a geometrical argument based on the fact that the Lie algebra of $\text{SU}(2)_L\times\text{SU}(2)_R$ is isomorphic to that of SO(4).
Your currents as given are malformed into singlets. They need isospin triplet matrices τ to make sense into the current algebra underlying the chiral picture:
$$\begin{cases} q_L \mapsto q_L'= M_L q_L = \exp{\left(- i {\boldsymbol{\theta}}_L \cdot \tfrac{\boldsymbol{\tau}}{2} \right)} q_L \\ q_R \mapsto q_R'= M_R q_R = \exp{\left(- i \boldsymbol{ \theta}_R \cdot \tfrac{\boldsymbol{\tau}}{2} \right)} q_R \end{cases},$$
where τ denote the three Pauli matrices in the flavor space and θL, θR are the corresponding rotation angles for the L and R groups, respectively.
The corresponding symmetry group $\text{SU}(2)_L\times\text{SU}(2)_R$ is the chiral group, controlled by the six conserved currents
$L_\mu^i = \bar q_L \gamma_\mu \tfrac{\tau^i}{2} q_L$, $R_\mu^i = \bar q_R \gamma_\mu \tfrac{\tau^i}{2} q_R$,
which can equally well be expressed in terms of the vector and axial-vector currents you should have written, $V_\mu^i = L_\mu^i + R_\mu^i$ , $A_\mu^i = R_\mu^i - L_\mu^i$.
The corresponding conserved charges generate the algebra of the chiral group,
$$\left[ Q_{I}^i, Q_{I}^j \right] = i \epsilon^{ijk} Q_I^k \qquad \qquad \left[ Q_{L}^i, Q_{R}^j \right] = 0,$$
with $I=L,R$, or, equivalently,
$$\left[ Q_{V}^i, Q_{V}^j \right] = i \epsilon^{ijk} Q_V^k, \qquad \left[ Q_{A}^i, Q_{A}^j \right] = i \epsilon^{ijk} Q_V^k, \qquad \left[ Q_{V}^i, Q_{A}^j \right] = i \epsilon^{ijk} Q_A^k.$$
Application of these commutation relations to hadronic reactions dominated current algebra calculations in the early seventies of the last century.
So the chiral field $U$ transforms differently on the left and the right,
$$M_L U M_R^\dagger=\exp(i\boldsymbol{\theta}_A\cdot \boldsymbol{\tau}/2 -i\boldsymbol{\theta}_V\cdot \boldsymbol{\tau}/2 )~ U ~\exp(i\boldsymbol{\theta}_A\cdot \boldsymbol{\tau}/2 +i\boldsymbol{\theta}_V\cdot \boldsymbol{\tau}/2 ).$$
θA= 0 , then, manifestly yields your vector transformation, while θV =0 the axial one.