We all know the basic example of school with series and parallel resistors, so they might be a good place to start.
Given two terminals $A$ and $B$ from a circuit, if the current that exists $A$ is the same as the one that enters $B$, then $$R_{eqAB} = \left|\frac{V_A-V_B}{I}\right|$$.
But what if in the real circuit not all the current exiting $A$ enters $B$? How would we calculate the equivalent current of the equivalent resistance? (The $I$ on the formula I posted above).
An example is the classical solution to the equivalent resistance of infinite grinds, they seem to understand the concept of equivalent resistance a bit better than the average high schooler on those solutions. Here is a question which explains it a bit further. There are much more examples, but the classic series/parallel ones we're used to, won't do the trick.