Can Maxwell's equations be used to define charge and current density? For example, we have $$ \nabla \cdot \vec{E} = 4\pi \rho $$ Can we rewrite this as $$ \rho = \frac{1}{4\pi} \nabla \cdot \vec{E} $$ and say that charge is nothing but $\frac{1}{4\pi} \nabla \cdot\vec{E}$? And could we similarly say that charge density is defined by $$ \vec{J} = \frac{1}{4\pi}\left(c \nabla\times\vec{B} - \frac{\partial \vec{E}}{\partial t}\right) $$
In other words, what's to stop us from dispensing altogether with charge and current density and thinking only in terms of electric and magnetic fields? Can we think of charge as a property of the electric field (i.e. a measure of its divergence)? Is there an experiment that suggests that charge and current density really are something distinct from the electric and magnetic fields?