There is no evidence that the global earthquake frequency has changed significantly over that last few centuries. Because the physical mechanism responsible for earthquakes is motion along faults, we believe there have been earthquakes for as long as the earth has had a crust and lithosphere comparable to today.
The oldest continental rocks dated, and ample geological evidence, indicate that plate tectonics has been ongoing for over 4 billion years. There may have been some variation in the rate of tectonic processes over time, but there is no evidence that plate tectonics is 'slowing down' because the earth is cooling.
You also should not assume that the temperature of the earth's core has been decreasing over this time. The radioactive decay and gravitational differentiation of the core could provide heat source in the earth's interior.
Prior to the formation of the crust, billions of years ago, the processes of the primordial earth would have been different than the processes responsible for earthquakes today.