"Is the equation of 1/4πε0 in Coulombs law a scalar?" an equation cannot be scalar.
"Also, does this equation equate to Coulombs constant?" a constant can equate an equation.
"In addition, why does Jefimenko use H=1/4π...
in his equations? What is the significance of 1/4π?"
To understand 1/4π you should look at the whole equation i.e.
$E = \frac{q}{\epsilon \;4 \pi r^2 }$
You should be able to recall that $4 \pi r^2$ is area of a sphere. This is because the electric field which is created by the charge $q$ is spherically symmetric.
"I can't tell if he's stating scalars are the 'cause' of vectors." Some quantities are scalar such as mass, temperature, and all the constants in physics. However, the scalar and vector quantities can be related using differentiation. Gradient of a scalar field (not a scalar, but a scalar field) is a vector and divergence of a vector field (again not a vector, but a vector field) is a scalar.
"He's using the terminology 'electric charge' and 'current' causing E and B fields" there are different ways to create E and B field. electric charges can create E field but this is not the only way to create E field. B field can be created by current.
E field can also be created by ∂B/∂t i.e. changing the B field.
"So how does ∂B/∂t relate to charges and currents?" you can use current (which is moving charges) to create B. then if you change the current (the speed at which the charges are moving), you create ∂B/∂t and it gives you E.
"Is it true that ∂B/∂t is equal a scalar?" ∂B/∂t is a vector because B is a vector. when a vector is multiplied or divided by a scalar the result is still a vector.