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For simplicity, I'll consider perhaps the simplest possible example of a gauge theory.

Consider a spontaneously broken ${\rm U(1)}$ gauge theory of a charged scalar field coupled to the electromagnetic field $$\mathscr{L}=(D_\mu\phi)^*(D^\mu\phi)-\mu^2\phi^*\phi-\lambda(\phi^*\phi)^2-\frac{1}{4}F_{\mu\nu}F^{\mu\nu}\tag{1}$$ with $\lambda>0$ and $\mu^2<0$. When the field $\phi$ with the polar parametrization $$\phi(x)=\frac{1}{\sqrt{2}}\big(v+h(x)\big)\exp{[i\zeta(x)/v]}\tag{2}$$ plugged into Eq.$(1)$, the field $\zeta$ disappeaears from the theory upon making a suitable gauge transformation. Therefore, there is no Goldstone mode.

Question What causes the Goldstone theorem not to be applicable here? I mean, is there a crucial assumption used in the derivation of Goldstone theorem fails here?

SRS
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FWIW, Goldstone's argument just yields that there is a massless mode. However, it could be an unphysical massless mode, cf. the BRST formalism. See also this & this related Phys.SE posts.

Qmechanic
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This is exactly the Higgs mechanism, which is what happens you have spontaneous symmetry breaking of a gauge symmetry. You are seeing the Goldstone mode get "eaten" by photon. You gauge-transform away the $\xi(x)$ field but you are left with a mass term for the photon, $\frac{1}{2}v^2 A_\mu(x) A^\mu(x)$.