Gravitational acceleration is a vector and thus has a direction.
But, at the center of a spherically symmetric mass distribution, there is no preferred direction while, if there were a non-zero gravitational acceleration vector, it would point in a direction.
Now, if one rotated the mass distribution through some angle, the acceleration vector should rotate along with it. Yet, the mass distribution would be indistinguishable from the non-rotated distribution and thus, there is no physical reason for the acceleration vector to have changed direction.
And so, from just a symmetry argument, we conclude the gravitational acceleration vector at the center of a spherical mass distribution must be the zero vector.