Why do the electrons start moving even if the dim light (less intense) of a specific frequency falls on the material ?
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Because the light is absorbed mostly as single photons. Two-photon absorption is also possible, but it is a much rarer event.
A single photon carries energy $\hbar\omega$. If it is not sufficient to "lift" the electron to higher allowed energy, such a photon is scattered elastically, without absorption.
The problem is that the electron is not alone, it is attracted to the nucleus. And it is not a classical particle, but a standing wave. Standing waves have distinct frequencies( energies). Thus, there is an energy threshold for promoting an electron to higher levels.
Vladimir Kalitvianski
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