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A faithful reproduction cannot be subject to copyright, if copyright of the original painting has expired.
Since this is an important topic for Wikipedia, the German-language Wikipedia covers copyright of images and photographs extensively in their guidelines:
Wikipedia: Bildrechte
They point out Directive (EU) 2019/790, which in Art. 14 says:
Member States shall provide that, when the term of protection of a
work of visual art has expired, any material resulting from an act of
reproduction of that work is not subject to copyright or related
rights, unless the material resulting from that act of reproduction is
original in the sense that it is the author's own intellectual
creation.
Wikipedia notes that this has been implemented in German law in 2021.