Both Italy and Greece are EU members.
In EU countries, copyright protects your intellectual property until 70 years after your death or 70 years after the death of the last surviving author in the case of a work of joint authorship. Source.
The ancient buildings you mention are therefore out of copyright, and you are free to model or reproduce them in any way you wish.
However if you derive data for these models from a modern source, such as photographs on the Web, you might have to consider the copyright on those sources. That's a more complicated question. The EU Copyright Directive includes some carve-outs analogous to fair use, which your usage might fit under. For instance, if you amalgamate lots of on-line photos of these monuments in order to derive texture maps for your models then you could probably claim the data mining exception. You might also argue that the creative input of the photographers in choosing a point of view and framing the picture are lost, and the only data you are using is the uncreative content derived from the monument itself. But these may turn out to be novel legal arguments which would require a court in each country to settle for certain.