For Gnome this solution seems to work to center opened application windows horizontally and vertically. Does Ubuntu Unity 16.04 have a similar feature?
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What yo need is CompizConfig Settings Manager (CCSM):
sudo apt install compizconfig-settings-manager
sudo apt install compiz-plugins
then open CCSM by going to the dash and type CCSM:

then go to Window management and window placement:
and play around till you've got exactly what you want!
Fabby
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