There is only a single "bash" executable. The directory /bin is now replaced by a symbolic link to /usr/bin. Therefore, both /bin/bash and /usr/bin/bash are the same executable.
Historically, bash as a core utility used to be in /bin. Hard drives were small, so there was a need to keep the system partition small. Core binaries were collected in /bin, which resided on the hard drive from which the system booted. A directory /usr/bin was then designed to host other binaries, that eventually were present on a partition on another drive, mounted later in the boot process.
Storage is nowadays plenty, so there is a tendency to do away with the historical split between /bin and /usr/bin. Many distributions started to move any executable to /usr/bin instead, but, for compatibility reasons, still have a /bin, which really is only a symbolic link to /usr/bin. This way, the traditional shebang #!/bin/bash continues to work, although /bin my disappear completely in the future.