I want to compare Coulomb scattering rate with Hubble's expansion rate.
To compute Coulomb scattering rate, I know that
$$ \Gamma = n_p\sigma v_{rel} $$
Here, $\sigma = \frac{e^{4}}{(4\pi\epsilon_o)^{2}}\frac{1}{m_e^{2}v_{rel}^{4}}4\pi(1+\frac{m_e}{m_p}) ln\Lambda$
I can approximate all the terms here. But I do not know what should I substitute for $v_{rel}$ given that I am dealing with early universe.
Failed attempts- I thought I can substitute $$ v_{rel} = |v_{p,rms}-v_{e,rems}| \approx v_{e,rms}$$ Since, $m_p \gg m_e$
Here, I can get rems values by using the fact that electron and photons are tightly coupled until Decoupling and hence $$ T_e = T_\gamma = T_o*z $$ where, $T_o = 2.7^{o}C$ is the CMB temperature today and $Z$ is the redshift.
However I noticed that with smaller redshifts a.k.a later times temperature $T$ will fall and hence $v_{rel}$ will fall. But I see that $$\Gamma \propto \frac{1}{v_{rel}^{3}}$$ Thus interaction rate increases with time. This makes no sense at all.
So, what should $v_{rel}$ be taken as? In online PDF's I noticed that they take it as a constant along with masses during analysis. How?
NOTE- After discussing with my professor and studying a bit more I came to know that this is actually a feature of Coloumb interaction. Its coupling increases actually increases over time. So the question is answered.