Please consider the sample output I got from  the free command in my Ubuntu 12.04:
           total       used       free     shared    buffers     cached
Mem:       8074640    6187480    1887160     377056     365128    2113156
-/+ buffers/cache:    3709196    4365444
Swap:     15998972      82120   15916852
The Mem used(kb_main_used) field value is now calculated like this:
used = total - free - cached - buffers
Previously, it used to be:
used = total - free
This change was introduced in the following commit https://gitlab.com/procps-ng/procps/commit/6cb75efef85f735b72e6c96f197f358f511f8ed9
An intermediate value:
buffers_plus_cached = buffers (kb_main_buffers) + cached (kb_main_cached) = 365128 + 2113156 = 2478284
+/- buffers/cache value is calculated like this:
buffers = kb_main_used - buffers_plus_cached = 6187480 - 2478284 = 3709196
/
cache = kb_main_free + buffers_plus_cached = 1887160 + 2478284 = 4365444
The new buff/cache value is calculates like this:
buff/cache = kb_main_buffers+kb_main_cached = 365128 + 2113156 = 2478284
This is the same as the buffers_plus_cached, used in previous versions, the difference is that previously it was used internally, and now its displayed directly, and the further calculated line, -/+ buffers/cache has been removed
For more info, please check these commits, where these changes were introduced:
https://gitlab.com/procps-ng/procps/commit/f47001c9e91a1e9b12db4497051a212cf49a87b1
https://gitlab.com/procps-ng/procps/commit/c9908b59712d1afd6b9bf7971ba1d8900ae5adb8
As of the new available field, for Linux kernels older than 2.6.27, its value is the same as the free value, but for the later versions of the Kernel, its a bit different:
Estimation of how much memory  is  available  for  starting  new
applications,  without swapping. Unlike the data provided by the
cache or free fields, this field takes into account  page  cache
and also that not all reclaimable memory slabs will be reclaimed
due to  items  being  in  use  (MemAvailable  in  /proc/meminfo,
available   on   kernels  3.14,  emulated  on  kernels  2.6.27+,
otherwise the same as free)
Courtesy:
http://manpages.ubuntu.com/manpages/xenial/en/man1/free.1.html
So, the specific answer to your questions would be:
- The new version of freeincludes buffers/cache in the calculations ofMem used/freevalues.
- The +/- buffers/cachevalue that used to be there in previous versions offreeis now available as:
- -/+ buffers/cache used= CurrentMem usedcolumn (Its calculation is detailed above)
- -/+ buffers/cache freeis available as the more accurate value in the current new columnavailable
 
N.B: The kb_* variable names are the internal names used in the source code.