The above changes the scroll bar for applications that use the gtk2 theme files. So does the gnome-color-chooser, (atleast the one in the current repository). For gtk3 applications, like gnome-terminal and gedit in 13.04 using gnome-fallback, one needs to change /usr/share/themes/Ambiance/gtk-3.0/gtk-widgets.css.
To do this
sudo gedit /usr/share/themes/Ambiance/gtk-3.0/gtk-widgets.css
and replace the * scrollbar * section with this:
/*************
 * scrollbar *
 *************/
.scrollbar,
.scrollbar.vertical {
    -GtkScrollbar-has-backward-stepper: 0;
    -GtkScrollbar-has-forward-stepper: 0;
    -GtkRange-slider-width: 14;
    border-radius: 3px;
    border-image: none;
}
.scrollbar.trough,
.scrollbar.trough.vertical {
    border-color: shade (@bg_color, 0.64);
}
.scrollbar.trough.horizontal {
}
.scrollbar.slider,
.scrollbar.slider:hover,
.scrollbar.button,
.scrollbar.slider.vertical,
.scrollbar.slider.vertical:hover,
.scrollbar.button.vertical {
    border-width: 1px;
    border-style: solid;
    border-color: shade (@bg_color, 0.4);
    background-image: -gtk-gradient (linear, left top, right top,
                                     from (shade (@button_bg_color, 0.76)),
                                     to (shade (@button_bg_color, 0.62)));
    box-shadow: inset 1px 0 shade (@button_bg_color, 0.85),
                inset -1px 0 shade (@button_bg_color, 0.62),
                inset 0 1px shade (@button_bg_color, 0.9),
                inset 0 -1px shade (@button_bg_color, 0.62);
}
.scrollbar.slider.horizontal,
.scrollbar.slider.horizontal:hover,
.scrollbar.button.horizontal {
    background-image: -gtk-gradient (linear, left top, left bottom,
                                     from (shade (@button_bg_color, 0.76)),
                                     to (shade (@button_bg_color, 0.62)));
    box-shadow: inset 1px 0 shade (@button_bg_color, 0.85),
                inset -1px 0 shade (@button_bg_color, 0.62),
                inset 0 1px shade (@button_bg_color, 0.9),
                inset 0 -1px shade (@button_bg_color, 0.62);
}
.scrollbar.button,
.scrollbar.button:insensitive {
}
This gives a scrollbar in gtk3 that looks like this: 

Which is kinda similiar to the one for gtk2 above. The small ticks and proper steppers is not included here though.